The horizontal axis is the depth of oxidation: the number of electrons transferred per molecule of glycerol. Each product occupies a characteristic position determined by stoichiometry. Lactic acid sits at 2 e⁻, glyceric at 4 e⁻, glycolic at 6 e⁻ (with a formate co-product from the C–C cleavage, which caps carbon yield to glycolic at two thirds), formate at 8 e⁻ (three molecules per glycerol), oxalic at 10 e⁻ and full mineralisation to carbonate at 14 e⁻.
This axis belongs to glycerine. The products shown, and the electron count at which each appears, are set by the structure of the glycerol molecule. Other carbon-rich feedstocks — other bio-waste streams, or the sugars behind Solution 3 — run on the same reactor but oxidise along their own pathways, giving a different set of products at different positions. The behaviour the model demonstrates, that tuning conditions narrows the product distribution, is what carries across; the specific products do not.
Carbon yield treats the products as competing parallel channels that divide the converted carbon between them, so the curves always sum to 100%. Mass yield rescales those channels by the theoretical mass recoverable per kilogramme of glycerol fed. Reaction progress shows the composition of the mixture itself travelling along the electron axis as oxidation proceeds.
This is an illustrative model, not a kinetic prediction. The channel shapes, their widths and the equal weighting between them are modelling choices made for clarity. Real selectivity profiles arise from competing reaction kinetics and will be neither symmetric nor uniform. The qualitative behaviour, that tuning conditions narrows the product distribution, is sound; the specific curve shapes are not measured.
The single axis simplifies a branched network, and mass yields are theoretical maxima that take no account of separation losses. The selectivity slider is an abstraction: no single control in the reactor maps onto it. It represents the headroom available through catalyst discovery and condition optimisation, which is precisely the development programme it is intended to motivate.